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108-37-2 - 1-Bromo-3-chlorobenzene, 99% - 3-Bromochlorobenzene - A14026 - Alfa Aesar

A14026 1-Bromo-3-chlorobenzene, 99%

CAS-Nummer
108-37-2
Synonyme
3-Bromochlorobenzene

Größe Preis ($) Menge Verfügbarkeit
100g 65,60
500g 254,00
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1-Bromo-3-chlorobenzene, 99%

MDL
MFCD00000568
EINECS
203-575-8

Chemische Eigenschaften

Formel
C6H4BrCl
Molmasse
191.46
Schmelzpunkt
-22°
Siedepunkt
195-196°
Flammpunkt
80°(176°F)
Dichte
1.630
Brechungsindex
1.5770
Löslichkeit
Not miscible in water.

Anwendungen

1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

Lei Shi; Yuanyuan Chu; Paul Knochel; Herbert Mayr. Kinetics of bromine-magnesium exchange reactions in substituted bromobenzenes. Journal of Organic Chemistry. 2009, 74,(7), 2760-2764.

 

M.Mahmoodi-Darian; S.X.Tian; S.Denifl; S.Matejcik; T.D.Mark; P.Scheier. Temperature dependence of dissociative electron attachment to 1-bromo-2-chlorobenzene and 1-bromo-3-chlorobenzene. International Journal of Mass Spectrometry. 2010, 293,(1-3), 51-55.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H315-H319-H335

Combustible liquid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260-P201-P280g-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1446353
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9005000

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