Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

107-05-1 - Allyl chloride, 98%, stab. with propylene oxide - 3-Chloro-1-propene - A14330 - Alfa Aesar

A14330 Allyl chloride, 98%, stab. with propylene oxide

CAS-Nummer
107-05-1
Synonyme
3-Chloro-1-propene

Größe Preis ($) Menge Verfügbarkeit
100ml 22,05
500ml 34,86
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Allyl chloride, 98%, stab. with propylene oxide

MDL
MFCD00000984
EINECS
203-457-6

Chemische Eigenschaften

Formel
C3H5Cl
Molmasse
76.53
Schmelzpunkt
-135°
Siedepunkt
44-46°
Flammpunkt
-28°(-18°F)
Dichte
0.939
Brechungsindex
1.4155
Löslichkeit
Soluble in water (3600 mg/L at 20°C), ethanol, ether, petroleum, acetone, chloroform, benzene, methanol and 2-prop.

Anwendungen

Allyl chloride is used as an alkylating agent. It is used in treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene.

Bemerkungen

Store at -20°C. Keep tightly closed in a dry and cool place. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Incompatible with strong oxidizing agents, boron trifluoride, sulfuric acid and nitric acid

Literaturverweise

Kenji Uneyama.; Nobuyoshi Kamaki.; Akihiko Moriya.; Sigeru Torii. Tin(II)-aluminum-promoted allylation of aldehydes with allyl chloride in an aqueous solvent system. J. Org. Chem. 1985, 50 (25), 5396-5399.

Farley Fisher.; Douglas E. Applequist. Synthesis of 1-Methylcyclopropene. J. Org. Chem. 1965, 30 (6), 2089-2090.

Lithiation with LDA in THF at -78o generatesɑ-chloroallyllithium which can be ɑ-alkylated with primary bromides in high yield. Displacement of the resulting allylic chloride with a dialkyl cuprate to give, stereoselectively, an (E)-alkene, has been used in a pheromone synthesis: J. Org. Chem., 45, 1504 (1981).

Treatment with sodium bis(trimethylsilyl)amide gives the strained, highly reactive alkene cyclopropene. For details and Diels-Alder reactions, see: J. Org. Chem., 61, 6462 (1996).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H341-H351-H373-H400-H302-H312-H332-H315-H319-H335

Highly flammable liquid and vapour. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P260-P201-P261-P273-P280-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,289
Beilstein
635704
Gefahrenklasse
3
Verpackungsgruppe
I
Harmonized Tariff Code
2903.29
TSCA
Yes
RTECS
UC7350000

Empfohlen

  • A11494

    1-Chlorobutane, 99+%
  • A11766

    Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide
  • A12575

    1-Methylimidazole, 99%
  • A15026

    Allyl alcohol, 98+%
  • 33337

    Magnesium sulfate, anhydrous, 99.5% min

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf