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75-84-3 - Neopentyl alcohol, 99% - 2,2-Dimethyl-1-propanol - A14390 - Alfa Aesar

A14390 Neopentyl alcohol, 99%

CAS-Nummer
75-84-3
Synonyme
2,2-Dimethyl-1-propanol

Größe Preis ($) Menge Verfügbarkeit
25g 33,12
100g 79,04
500g 311,20
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Neopentyl alcohol, 99%

MDL
MFCD00004682
EINECS
200-907-3

Chemische Eigenschaften

Formel
(CH3)3CCH2OH
Molmasse
88.15
Schmelzpunkt
52-56°
Siedepunkt
111-114°
Flammpunkt
36°(96°F)
Dichte
0.818
Löslichkeit
Soluble in water at (20°C 40 g/L), alcohol, and ether. Solubility in methanol is almost transparent.

Anwendungen

It is used in the Mitsunobu reaction of methyl salicylate coupling of sterically hindered substrates.

Bemerkungen

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Sudhakar Bhandaru, et al. Synthesis of a C14',15' dihydro derivative of the south hexacyclic steroid unit of cephalostatin 1. Part I : regiospecific Rh[II]-mediated intermolecular oxygen alkylation of a primary neopentyl alcohol.Tetrahedron Lett.,1995,36(46), 8347-8350.

J. D. Slagle, et al. Mechanism of the triphenylphosphine-tetrachloromethane-alcohol reaction: pericyclic or clustered ion pairs?J. Org. Chem.,1981,46(17), 3526-3530.

A method has been described for conversion to the iodide using a combination of methyl iodide and triphenyl phosphite: Org. Synth. Coll., 6, 830 (1988).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H228

Flammable solid.

Sicherheitshinweise: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Weitere Referenzen

Merck
14,6457
Beilstein
1730984
Gefahrenklasse
4.1
Verpackungsgruppe
II
Harmonized Tariff Code
2905.19
TSCA
Yes

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