A14572 1,2,3-Trimethoxybenzene, 98+%
SDS
| Stock No. | Größe | Preis ($) | Menge | Verfügbarkeit |
|---|---|---|---|---|
| A14572-14 | 25g | 28,50 |
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| A14572-22 | 100g | 79,50 |
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| A14572-36 | 500g | 388,00 |
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1,2,3-Trimethoxybenzene, 98+%
Chemische Eigenschaften
Anwendungen
1,2,3-Trimethoxybenzene was used to study the effect of solvent on photo induced electron-transfer reactions, on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.
Bemerkungen
Literaturverweise
A Stuart; T Paterson; B Roth; E Aig. 2,4-diamino-5-benzylpyrimidines and analogues as antibacterial agents. 6. A one-step synthesis of new trimethoprim derivatives and activity analysis by molecular modeling. Journal of Medicinal Chemistry. 1983, 26 (5), 667-673.
Liming Zhang; Göran Gellerstedt. Quantitative 2D HSQC NMR determination of polymer structures by selecting suitable internal standard references. JMagnetic Resonance in Chemistry. 2007, 45 (1), 37-45.
Direct dilithiation with n-BuLi/TMEDA gave poor results, but a sequence involving monolithiation, silylation and further lithiation at the 6-position gave the 4,6-disilyl derivative in 62% yield: J. Org. Chem., 49, 4657 (1984).
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