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583-60-8 - 2-Methylcyclohexanone, 98% - A14741 - Alfa Aesar

A14741 2-Methylcyclohexanone, 98%

CAS-Nummer
583-60-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100ml 48,60
500ml 158,59
2500ml 677,24
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2-Methylcyclohexanone, 98%

MDL
MFCD00001635
EINECS
209-513-6

Chemische Eigenschaften

Formel
C7H12O
Molmasse
112.17
Schmelzpunkt
-14°
Siedepunkt
162-163°
Flammpunkt
46°(114°F)
Dichte
0.925
Brechungsindex
1.4480
Löslichkeit
Insoluble in water. Soluble in methanol and diethyl ether.

Anwendungen

2-Methylcyclohexanone is used as a fragrant and flavoring agent. It can also be used for the preparation of a novel pladienolide analog scaffold. Also used as a solvent.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

Ahmed Atlamsani; Jean Marie Bregeault; Mahfoud Ziyad. Oxidation of 2-methylcyclohexanone and cyclohexanone by dioxygen catalyzed by vanadium-containing heteropolyanions. J. Org. Chem. 1993, 58, (21),5663-5665

 

Ivan Jabin; Gilbert Revial; Alain Tomas; Pascale Lemoine; Michel Pfau. Diastereoselectivity and enantioselectivity in the addition of chiral imines of 2-methylcyclohexanone to crotonic and methacrylic acid esters. Tetrahedron: Asymmetry. 1995, 6, (7),1795-1812

For use in the asymmetric synthesis of a steroid building block, see: Org. Synth. Coll., 9, 610 (1998); for reaction scheme. see (S)-(-)-1-Phenyl­ethyl­amine, A12632.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H332

Flammable liquid and vapour. Harmful if inhaled.

Sicherheitshinweise: P210-P261-P280-P240-P241-P303+P361+P353-P304+P340-P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
506751
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2914.22
TSCA
Yes
RTECS
GW1750000

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