Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

4376-18-5 - Methyl hydrogen phthalate, 97% - Benzene-1,2-dicarboxylic acid monomethyl ester - Monomethyl phthalate - A14780 - Alfa Aesar

A14780 Methyl hydrogen phthalate, 97%

CAS-Nummer
4376-18-5
Synonyme
Benzene-1,2-dicarboxylic acid monomethyl ester
Monomethyl phthalate

Größe Preis ($) Menge Verfügbarkeit
10g 46,17
50g 154,39
250g 501,82
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Methyl hydrogen phthalate, 97%

MDL
MFCD00002466
EINECS
224-476-6

Chemische Eigenschaften

Formel
C9H8O4
Molmasse
180.16
Schmelzpunkt
81-84°
Löslichkeit
Insoluble in water.

Anwendungen

Methyl hydrogen phthalate is used as a phthalate ester metabolite, linked to precocious puberty.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents.

Literaturverweise

ML Bender.; F Chloupek.; MC Neveu. Intramolecular Catalysis of Hydrolytic Reactions. III. Intramolecular Catalysis by Carboxylate Ion in the Hydrolysis of Methyl Hydrogen Phthalate1, 2. J. Am. Chem. Soc.1958, 80 (20), 5384-5387.

V Rao.; PV Ashokan.; MH Shridhar. Studies on the compatibility and specific interaction in cellulose acetate hydrogen phthalate(CAP) and poly methyl methacrylate (PMMA) blend. Polymer.1999, 40 (25), 7167-7171.

Undergoes a modified Curtius rearrangement via a mixed anhydride. The resulting isocyanate has been cyclized with, e.g. alanine to give chiral quinazoline-2,4-dione derivatives: Heterocycles, 36, 1305 (1993):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2048766
Harmonized Tariff Code
2917.34
TSCA
No

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf