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4659-45-4 - 2,6-Dichlorobenzoyl chloride, 98% - A14839 - Alfa Aesar

A14839 2,6-Dichlorobenzoyl chloride, 98%

CAS-Nummer
4659-45-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 40,43
50g 162,00
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2,6-Dichlorobenzoyl chloride, 98%

MDL
MFCD00000662
EINECS
225-102-4

Chemische Eigenschaften

Formel
C7H3Cl3O
Molmasse
209.46
Schmelzpunkt
15-18°
Siedepunkt
130-132°/15mm
Flammpunkt
>110°(230°F)
Dichte
1.463
Brechungsindex
1.5600
Sensitivität
Moisture Sensitive
Löslichkeit
Miscible with alcohol, ether and acetone. Slightly miscible with heptane. Immiscible with water.

Anwendungen

2,6-Dichlorobenzoyl chloride acts as an important intermediate in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. It is employed in the substrate activity screening method for the rapid development of novel substrates and their conversion into non-peptidic inhibitors of Cys and Ser proteases. It is also used in the preparation of 1-acyliridoles and (-)-aspicilin. In addition to this, it undergoes esterification of (fluoren-9-ylmethoxy)carbonyl (Fmoc)-amino acids to 4-alkoxybenzyl alcohol polystyrene.

Bemerkungen

Moisture sensitive. Incompatible with alcohols, oxidizing agents and strong bases.

Literaturverweise

Furse, S.; Mak, L.; Tate, E. W.; Templer, R. H.; Ces, O.; Woscholski, R.; Gaffney, P. R. Synthesis of unsaturated phosphatidylinositol 4-phosphates and the effects of substrate unsaturation on SopB phosphatase activity. Org. Biomol. Chem. 2015, 13 (7), 2001-2011.

Zhang, T.; Paluch, K.; Scalabrino, G.; Frankish, N.; Healy, A. M.; Sheridan, H. Molecular structure studies of (1S,2S)-2-benzyl-2,3-dihydro-2-(1H-inden-2-yl)-1H-inden-1-ol. J. Mol. Struct. 2015, 1083, 286-299.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
639531
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2916.39
TSCA
No

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