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109-09-1 - 2-Chloropyridine, 99% - A14866 - Alfa Aesar

A14866 2-Chloropyridine, 99%

CAS-Nummer
109-09-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
100g 25,00
500g 92,80
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2-Chloropyridine, 99%

MDL
MFCD00006228
EINECS
203-646-3

Chemische Eigenschaften

Formel
C5H4ClN
Molmasse
113.55
Schmelzpunkt
-46°
Siedepunkt
167-170°
Flammpunkt
65°(149°F)
Dichte
1.208
Brechungsindex
1.5320
Löslichkeit
Soluble in water (27g/L).

Anwendungen

2- Chloropyridine is used as an intermediate chemical in the production of various pyrithione, for use in cosmetics, personal care products and pharmaceutical products.

Bemerkungen

Keep container tightly closed. Store away from oxidizing agents.

Literaturverweise

Sabine Choppin.; Philippe Gros.; Yves For. Unusual C-6 Lithiation of 2-Chloropyridine-Mediated by BuLi-Me2N(CH2)2OLi. New Access to 6-Functional-2-chloropyridines and Chloro-bis-heterocycles. Org. Lett. 2002, 2, (6), 803-805.

Meriç Bakiler.; I.V. Maslov.; Sevim Akyüzc.Theoretical study of the vibrational spectra of 2-chloropyridine metal complexes. I. Calculation and analysis of the IR spectrum of 2-chloropyridine. Journal of Molecular Structure. 1999, 475, (1), 83-92.

Reaction with the unimetal suberbase complex formed from 2 mol of n-BuLi and I mol of 2-(Dimethyl­amino)­ethanol, B23616, in hexane, gives products resulting from apparent metallation at the 6-position, providing useful access to 6-functionalized 2-chloropyridines: Org. Lett., 2, 803 (2000). See also 2-Methoxypyridine, A13675, for a similar effect.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H301-H310-H330-H315-H318-H335

Combustible liquid. Toxic if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
105788
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
US5950000

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