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768-90-1 - 1-Bromoadamantane, 99% - 1-Adamantyl bromide - A14893 - Alfa Aesar

A14893 1-Bromoadamantane, 99%

CAS-Nummer
768-90-1
Synonyme
1-Adamantyl bromide

Größe Preis ($) Menge Verfügbarkeit
25g 30,70
100g 100,00
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1-Bromoadamantane, 99%

MDL
MFCD00074721
EINECS
212-200-7

Chemische Eigenschaften

Formel
C10H15Br
Molmasse
215.14
Schmelzpunkt
117-121°
Löslichkeit
It is soluble in organic solvents and insoluble in water.

Anwendungen

1-Bromoadamantane is an important intermediate, used in synthesizing medicines and new materials etc.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Moisture sensitive. Keep away from Strong oxidizing agents.

Literaturverweise

SL Regen .;  JJ Besse .;  J McLick. Solid-phase cosolvents. Triphase catalytic hydrolysis of 1-bromoadamantane. Journal of the American Chemical. 1979 101, (1), 116-120.

SL Regen.; L Dulak. Solid-phase cosolvents. Journal of the American Chemical society. 197799, (2), 623-625.

Reduction with Tri-n-butyl­tin hydride, A13298, generates the 1-adamantyl radical which, e.g. adds to Michael acceptors in good yield: J. Org. Chem., 53, 1285 (1988).

With activated Ca metal (prepared from CaBr2 and Li biphenylide), forms an organocalcium reagent which reacts with ketones to give tertiary alcohols; the preparation and reactivity of these intermediates is discussed: Org. Synth. Coll., 9, 9 (1998).

Undergoes Heck-type coupling with styrenes and arenes, catalyzed by Pd on carbon: Synthesis, 148 (1998).

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1098857
Harmonized Tariff Code
2903.89
TSCA
No

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