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5292-43-3 - tert-Butyl bromoacetate, 98% - Bromoacetic acid tert-butyl ester - A14917 - Alfa Aesar

A14917 tert-Butyl bromoacetate, 98%

CAS-Nummer
5292-43-3
Synonyme
Bromoacetic acid tert-butyl ester

Größe Preis ($) Menge Verfügbarkeit
10g 21,84
50g 87,57
250g 310,03
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tert-Butyl bromoacetate, 98%

MDL
MFCD00000188
EINECS
226-133-6

Chemische Eigenschaften

Formel
C6H11BrO2
Molmasse
195.06
Siedepunkt
175°
Flammpunkt
49°(120°F)
Dichte
1.330
Brechungsindex
1.4450
Löslichkeit
Miscible with ethanol, chloroform and ethyl acetate. Immiscible with water.

Anwendungen

tert-Butyl bromoacetate is used as an intermediate in the production of dyes, pharmaceuticals, agrochemicals and in organic compounds. It finds application as an alkylating agent. It plays an important role to prepare (2-oxo-4-vinyl-azetidin-1-yl)-acetic acid tert-butyl ester and in collagenase inhibitors synthesis.

Bemerkungen

Hygroscopic. Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Becherer, T.; Grunewald, C.; Engelschalt, V.; Multhaup, G.; Risse, T.; Haag, R. Polyglycerol based coatings to reduce non-specific protein adsorption in sample vials and on SPR sensors. Anal. Chim. Acta 2015, 867, 47-55.

Kamalov, M.; Harris, P. W.; Hartinger, C. G.; Miskelly, G. M.; Cooper, G. J.; Brimble, M. A. Physicochemical studies on the copper(II) binding by glycated collagen telopeptides. Org. Biomol. Chem. 2015, 13 (10), 3058-3063.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318-H226-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Flammable liquid and vapour. Harmful if swallowed.

Sicherheitshinweise: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Beilstein
1753010
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2915.90
TSCA
Yes

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