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Bromo Cyclopropane is primarily used an intermediate in the manufacture of pharmaceutical and agrochemical products. It is also used in the production of cyclopropyl boric acid. It is used as an intermediate in organic synethesis.
John F. Garst.; Ferenc Ungvary.; Rajnish Batlaw.; Kathryn Easton Lawrence. Solvent attack in Grignard reagent formation from bromocyclopropane and 1-bromohexane in diethyl ether. J. Am. Chem. Soc. 1991, 113, (14), 5392-5397.
CJ Wurrey.; RJ Berry.; YY Yeh.; TS Little. Vibrational spectra of bromocyclopropane Journal of Raman Spectroscopy. 1983, 14, (2), 87-92.
The Grignard reagent functions as an allyl anion equivalent in the reaction with thioacetals catalyzed by Dichlorobis(triphenylphosphine)nickel(II), 13930: J. Am. Chem. Soc., 111, 9119 (1989):
The lithio-derivative reacts with Bis(cyclopentadienyl)titanium dichloride, A11456, to give bis(cyclopropyl)titanocene, which reacts with carbonyl compounds to give alkylidenecyclopropane derivatives: Tetrahedron Lett., 34, 943 (1993). Similarly, esters and lactones give enol ethers and acetylenes give vinylcyclopropanes.
Gefahrenhinweise (EU): H225-H315-H319-H335
Highly flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
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