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622-78-6 - Benzyl isothiocyanate, 98% - A15008 - Alfa Aesar

A15008 Benzyl isothiocyanate, 98%

CAS-Nummer
622-78-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 22,61
25g 66,80
100g 212,80
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Benzyl isothiocyanate, 98%

MDL
MFCD00004819
EINECS
210-753-9

Chemische Eigenschaften

Formel
C6H5CH2NCS
Molmasse
149.22
Siedepunkt
242-243°
Flammpunkt
>110°(230°F)
Dichte
1.125
Brechungsindex
1.6030
Sensitivität
Moisture Sensitive
Löslichkeit
Hydrolyzes in water.

Anwendungen

Benzyl isothiocyanate is used in a synthesis of 2-phenylpyrimidine-4-thiones from Benzoyl­acetonitrile. Benzyl isothiocyanate has been used in the preparation of S-(N-benzylthiocarbamoyl)-L-glutathione and S-(N-benzylthiocarbamoyl)-L-cysteine.

Bemerkungen

Moisture Sensitive. Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

I.M. Bruggeman.; J.H.M. Temmink.; P.J. van Bladeren. Glutathione- and cysteine-mediated cytotoxicity of allyl and benzyl isothiocyanate. Toxicology and Applied Pharmacology. 1986, 83, (2), 349-359.

Chung-Shih Tang. Benzyl isothiocyanate of papaya fruit . Phytochemistry. 1971, 10, (1), 117-121.

Used in a synthesis of 2-phenylpyrimidine-4-thiones from Benzoyl­acetonitrile, A14473: Synthesis, 775 (1989).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H331-H302-H312-H317-H334-H351-H314-H318

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. May cause an allergic skin reaction. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Suspected of causing cancer. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P285-P201-P261-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. In case of inadequate ventilation wear respiratory protection. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
386135
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2930.90
TSCA
Yes
RTECS
NX8250000

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