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Trimethylacetaldehyde is used as a stereoselective synthesis application. It is also used as a building block used in aldol condensation reactions. It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and Dyestuff.
Anna K. Szardenings.; Timothy S. Burkoth.; Gary C. Look.; David A. Campbell. A Reductive Alkylation Procedure Applicable to Both Solution- and Solid-Phase Syntheses of Secondary Amines. J. Org. Chem. 1996, 61, (19), 6720-6722.
Samiran Bhattacharjee.; Kwang-Eun Jeong.; Soon-Yong Jeong.; Wha-Seung Ahnl. Synthesis of a sulfonato-salen-nickel(II) complex immobilized in LDH fortetralin oxidation. New J. Chem. 2010, 34, 156-162.
Derivatizing agent for amino acids, forming oxazolidinones as volatile derivatives for GC: Anal. Biochem., 49, 442 (1972); Aust. J. Biol. Sci., 26, 831 (1973).
For formation of the fused pyrrolidino-oxazolidinone from L-proline, catalyzed by trifluoroacetic acid, and use of the product in a synthesis of ɑ-branched amino acids, see: Org. Synth. Coll., 9, 626 (1998):
For use in the protection of asparagine as a tetrahydropyrimidinone derivative, see: Org. Synth. Coll., 9, 17 (1998). For use of this system in ɑ-alkylation of (S)-asparagine with self-regeneration of the stereogenic center, see: J. Org. Chem., 63, 4706 (1998).
Promotes the epoxidation of alkenes with molecular oxygen: Tetrahedron Lett., 33, 6827 (1992).
The imine formed with ethylamine has been used to convert aryl chlorides to the hindered tertiary amides: N-ethyl-N-(1-methoxy-2,2-dimethylpropyl)benzamides, which can be ortho metallated cleanly at higher temperatures than other amide systems: J. Org. Chem., 60, 8417 (1995).
Gefahrenhinweise (EU): H225
Highly flammable liquid and vapour.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Take precautionary measures against static discharge. Store in a well-ventilated place.