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107-18-6 - Allyl alcohol, 98+% - 2-Propen-1-ol - 3-Hydroxy-1-propene - A15026 - Alfa Aesar

A15026 Allyl alcohol, 98+%

CAS-Nummer
107-18-6
Synonyme
2-Propen-1-ol
3-Hydroxy-1-propene

Größe Preis ($) Menge Verfügbarkeit
100ml 15,35
500ml 25,21
2500ml 90,90
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Chemische Eigenschaften

Formel
C3H6O
Molmasse
58.08
Schmelzpunkt
-129°
Siedepunkt
95-97°
Flammpunkt
22°(71°F)
Dichte
0.852
Brechungsindex
1.4130
Löslichkeit
Miscible with water.

Anwendungen

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Bemerkungen

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Literaturverweise

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H301-H311-H331-H315-H319-H335-H400

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Very toxic to aquatic life.

Sicherheitshinweise: P210-P261-P273-P280-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,286
Beilstein
605307
Gefahrenklasse
6.1
Verpackungsgruppe
I
Harmonized Tariff Code
2905.29
TSCA
Yes
RTECS
BA5075000

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