Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

4206-67-1 - (Iodomethyl)trimethylsilane, 99% - Trimethylsilylmethyl iodide - A15120 - Alfa Aesar

A15120 (Iodomethyl)trimethylsilane, 99%

CAS-Nummer
4206-67-1
Synonyme
Trimethylsilylmethyl iodide

Größe Preis ($) Menge Verfügbarkeit
10g 75,60
50g 247,20
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(Iodomethyl)trimethylsilane, 99%

MDL
MFCD00001077
EINECS
224-123-6

Chemische Eigenschaften

Formel
C4H11ISi
Molmasse
214.12
Siedepunkt
140-142°
Flammpunkt
31°(88°F)
Dichte
1.443
Brechungsindex
1.4915
Sensitivität
Light Sensitive
Löslichkeit
Difficult to mix.

Anwendungen

(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

Bemerkungen

Light Sensitive. Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

Literaturverweise

Motoo Tori.; Chiho Makino.; Kenji Hisazumi.; Masakazu Sono.; Katsuyuki Nakashima. Synthesis of a homochiral ketone having a pinguisane skeleton using phenylethylamine as a chiral auxiliary: a formal total synthesis of deoxopinguisone. Tetrahedron: Asymmetry. 2001, 12, (2), 301-307.

Dale L. Boger.; Louis R. Cerbone.; Daniel Yohannes. Oxidative coupling of methyl 6-hydroxyindole-2-carboxylate with primary amines. Preparation of 2-substituted methyl pyrrolo[2,3-e]benzoxazole-5-carboxylates. J. Org. Chem. 1988, 53, (21), 5163-5166.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1731485
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2931.90
TSCA
No

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf