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580-13-2 - 2-Bromonaphthalene, 98+% - A15300 - Alfa Aesar

A15300 2-Bromonaphthalene, 98+%

CAS-Nummer
580-13-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 34,51
25g 121,50
100g 393,60
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2-Bromonaphthalene, 98+%

MDL
MFCD00004051
EINECS
209-452-5

Chemische Eigenschaften

Formel
C10H7Br
Molmasse
207.08
Schmelzpunkt
53-57°
Siedepunkt
281-282°
Flammpunkt
112°(233°F)
Dichte
1.605
Löslichkeit
Slightly soluble in water.

Anwendungen

2-Bromonaphthalene is used as a raw material in the preparation of biaryls through Suzuki cross coupling reaction. Further, it plays a vital role in the preparation of dyes. It is also used to study potential tumorigenicity.

Bemerkungen

Store in a cool place. Incompatible with strong oxidizing agents.

Literaturverweise

The Grignard reagent has been reacted with N-benzylproline methyl ester in the synthesis of oxazaborolidines (compare (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219) for use as chiral auxiliaries: J. Org. Chem., 56, 442 (1991).

Hopkins, B. A.; Garlets, Z. J.; Wolfe, J. P. Development of Enantioselective Palladium-Catalyzed Alkene Carboalkoxylation Reactions for the Synthesis of Tetrahydrofurans. Angew. Chem. Int. Ed. 2015, 54 (45), 13390-13392

Xu, L.; Suo, H.; Liang, X.; Wang, L.; Guo, Y.; Jiang, S. Au nanoparticle decorated graphene oxide as a novel coating for solid-phase microextraction. RSC Adv. 2015, 5 (52), 41536-41543.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H319

Harmful if swallowed. Causes serious eye irritation.

Sicherheitshinweise: P280-P264-P270-P305+P351+P338-P301+P312-P337+P313-P330-P501a

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,1426
Beilstein
1858110
Harmonized Tariff Code
2903.99
TSCA
Yes

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