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100-00-5 - 1-Chloro-4-nitrobenzene, 98+% - 4-Nitrochlorobenzene - A15396 - Alfa Aesar

A15396 1-Chloro-4-nitrobenzene, 98+%

CAS-Nummer
100-00-5
Synonyme
4-Nitrochlorobenzene

Größe Preis ($) Menge Verfügbarkeit
250g 18,33
1000g 40,07
5000g 124,00
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1-Chloro-4-nitrobenzene, 98+%

MDL
MFCD00007285
EINECS
202-809-6

Chemische Eigenschaften

Formel
C6H4ClNO2
Molmasse
157.56
Schmelzpunkt
82-86°
Siedepunkt
238-242°
Flammpunkt
127°(260°F)
Dichte
1.515
Löslichkeit
Soluble in boiling hot ethanol, ether, toluene, acetone, organic solvents and carbon disulfide. Sparingly soluble in cold alcohol. Insoluble in water.

Anwendungen

1-Chloro-4-nitrobenzene is an important intermediate used in the preparation of 2,4-dinitrochlorobenzene and 3,4-dichloronitrobenzene. It is used as a raw material in the preparation of 4-nitrodiphenylamine, 4-chloroaninline and (4-[(4-aminobenzene)sulfonyl]aniline). It serves as a common antioxidant, which is found in rubber.

Bemerkungen

Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

The Cl substituent is activated to nucleophilic substitution by the p-nitro-group, and can be displaced under relatively mild conditions. For displacement by phenoxide, see: Org. Synth. Coll., 2, 445 (1943). For displacement by alkoxide in good yield, in the presence of TBAB or 18-crown-6, see: J. Org. Chem., 48, 3022 (1983).

Büldt, L. A.; Prescimone, A.; Neuburger, M.; Wenger, O. S. Photoredox Properties of Homoleptic d6 Metal Complexes with the Electron-Rich 4,4',5,5'-Tetramethoxy-2,2'-bipyridine Ligand. Eur. J. Inorg. Chem. 2015, 2015 (28), 4666-4677.

Zhuo, L.; Kou, K.; Yao, P.; Wu, G.; Wang, Y. Preparation and thermal decomposition kinetics research of pyridine-containing polyimide. J. Therm. Anal. Calorim. 2015, 119 (3), 2039-2051.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H331-H341-H351-H373-H411

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Suspected of causing genetic defects. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects.

Sicherheitshinweise: P260-P201-P261-P273-P280-P281-P301+P310-P361-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Remove/Take off immediately all contaminated clothing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,2151
Beilstein
508691
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2904.90
TSCA
Yes
RTECS
CZ1050000

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