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3030-47-5 - 1,1,4,7,7-Pentamethyldiethylenetriamine, 98% - PMDTA - A15433 - Alfa Aesar

A15433 1,1,4,7,7-Pentamethyldiethylenetriamine, 98%

CAS-Nummer
3030-47-5
Synonyme
PMDTA

Größe Preis ($) Menge Verfügbarkeit
25g 47,28
100g 139,50
500g 536,80
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1,1,4,7,7-Pentamethyldiethylenetriamine, 98%

MDL
MFCD00014876
EINECS
221-201-1

Chemische Eigenschaften

Formel
C9H23N3
Molmasse
173.30
Schmelzpunkt
<-20°
Siedepunkt
199°
Flammpunkt
72°(161°F)
Dichte
0.830
Brechungsindex
1.4420
Sensitivität
Air & Moisture Sensitive
Löslichkeit
Miscible in water.

Anwendungen

Used as ligand in NMR study of complexation/aggregation with neopentyllithium1 and in the study of ligand effects on the selectivity of CO2 incorporation into &#945;,&#969;-diynes

Bemerkungen

Air & Moisture Sensitive. Store under inert gas. Incompatible with strong oxidizing agents, strong acids.

Literaturverweise

L. Banci; A. Bencini; D. Gatteschi. Anisotropic exchange in transition-metal dinuclear complexes. 3. Bis(.mu.-(1,3-azido)bis(1,1,4,7,7-pentamethyldiethylenetriamine)dicopper(II) bis(tetraphenylborate).Inorg. Chem.1984, 23 (14), 2138-2141.

Hou Chen; Delong Liu; Yuting Song; Rongjun Qu and Chunhua Wang. ARGET ATRP of acrylonitrile with ionic liquid as reaction media and 1,1,4,7,7-pentamethyldiethylenetriamine as both ligand and reducing agent in the presence of air.Polymers for Advanced Technologies.2011, 22 1513-1517.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H311-H302-H314-H227

Toxic in contact with skin. Harmful if swallowed. Causes severe skin burns and eye damage. Combustible liquid.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1741396
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2921.29
TSCA
Yes
RTECS
IE2100000

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