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Methyl 4-bromobenzoate is used as a starting material in the synthesis of three-carbon-bridged 5-substituted furo[2,3-d]pyrimidine and 6-substituted pyrrolo[2,3-d]pyrimidine and methyl 4-tri-n-butylstannylbenzoate. It is also used to stimulate microbial dechlorination of polychlorinated biphenyls. Further, it is used in the preparation of stable radioiodinating reagent to label monoclonal antibodies for radiotherapy of cancer.
Frieman, B. A. An environmentally-friendly one-pot synthesis of 4-sulfonyl benzoic acids. Tetrahedron Lett. 2014, 55 (22), 3295-3298.
Cui, X.; Wang, S.; Zhang, Y.; Deng, W.; Qian, Q.; Gong, H. Nickel-catalyzed reductive allylation of aryl bromides with allylic acetates. Org. Biomol. Chem. 2013,< span class="italictxt">11 (19), 3094-3097.