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4-Methoxy-o-phenylenediamine is widely used as an intermediate in organic synthesis and pharmaceuticals. It is an important precursor for the synthesis of other heterocyclic compounds. It is used in the determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as a derivatizing reagent by High-performance liquid chromatography (HPLC).
Ojeda, A. G.; Wrobel, K.; Escobosa, A. R. C.; Sevilla, E. G.; Wrobel, K. High-performance liquid chromatography determination of glyoxal, methylglyoxal, and diacetyl in urine using 4-methoxy-o-phenylenediamine as derivatizing reagent. Anal. Biochem. 2014, 449, 52-58.
Vadagaonkar, K. S.; Kalmode, H. P.; Mrugan, K.; Chaskar, A. C. I2 catalyzed tandem protocol for synthesis of quinoxalines via sp3, sp2and sp C-H functionalization. RSC Adv. 2015, 5 (8), 5580-5590.
Gefahrenhinweise (EU): H302-H312-H332-H315-H319-H335
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.