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1193-18-6 - 3-Methyl-2-cyclohexen-1-one, 98% - A15704 - Alfa Aesar

A15704 3-Methyl-2-cyclohexen-1-one, 98%

CAS-Nummer
1193-18-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 67,36
25g 118,16
50g 209,18
100g 423,07
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3-Methyl-2-cyclohexen-1-one, 98%

MDL
MFCD00001581
EINECS
214-769-7

Chemische Eigenschaften

Formel
C7H10O
Molmasse
110.15
Siedepunkt
199-200°
Flammpunkt
68°(154°F)
Dichte
0.971
Brechungsindex
1.4940
Löslichkeit
Soluble in alcohol. Insoluble in water.

Anwendungen

3-Methyl-2-cyclohexen-1-one was used in the synthesis of 19-nor-1α, 25-dihydroxyvitamin D(3) derivatives. It was also used in sex pheromone of the Douglas-fir beetle. Used in nut flavor.

Bemerkungen

Store in cool, well ventilated area. Keep container tightly closed. Store away form oxidizing agent.

Literaturverweise

X Zhou; G D Zhu; D Van Haver; M Vandewalle; P J De Clercq; A Verstuyf; R Bouillon. Synthesis, biological activity, and conformational analysis of four seco-D-15,19-bisnor-1alpha,25-dihydroxyvitamin D analogues, diastereomeric at C17 and C20. Journal of Medicinal Chemistry. 1999, 42 (18), 3539-3556.

Donald S. Noyce, Malcolm. Evett. Mechanism of the acid-catalyzed double bond migration in 3-cyclohexen-1-one and 3-methyl-3-cyclohexen-1-one. J. Org. Chem. 1972, 37 (3), 394-397.

For photochemical (2 + 2) photocycloaddition reaction with ethylene, as a general method for synthesis of fused cyclobutane systems, see: Org. Synth. Coll., 7, 315 (1990).

For conversion to the silyl enol ether and stereoselective aldol-type coupling, see: Tetrahedron, 45, 6101 (1989):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H227

Harmful if swallowed. Combustible liquid.

Sicherheitshinweise: P210-P280-P264-P270-P301+P312-P330-P370+P378a-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1560601
Harmonized Tariff Code
2914.29
TSCA
Yes
RTECS
GW7340000

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