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Isophthalaldehyde is used in the synthesis of binuclear ruthenium complex. It participates in base-catalyzed Knoevenagel condensation reaction.
E. Hadjoudis.; T. Dziembowska.; Z. Rozwadowski. Photoactivation of the thermochromic solid di-anil of 2-hydroxy-5-methyl-isophthalaldehyde in β-cyclodextrin..J. Photochem. Photobiol., A 1999, 128 (1-3), 97-99 .
Jürgen Lorösch.; Wolfgang Haase. Crystal structure and magnetic properties of an asymmetric bridged binuclear Cu(II)-complex with a macrocyclic ligand derived from 2-hydroxy-5-methyl-isophthalaldehyde and histamine.Inorg. Chim. Acta. 1985, 108 (1),35-40 .