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772-31-6 - Cyclopropyl 4-fluorophenyl ketone, 98% - (4-Fluorobenzoyl)cyclopropane - A15852 - Alfa Aesar

A15852 Cyclopropyl 4-fluorophenyl ketone, 98%

CAS-Nummer
772-31-6
Synonyme
(4-Fluorobenzoyl)cyclopropane

Größe Preis ($) Menge Verfügbarkeit
5g 21,76
25g 72,76
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Cyclopropyl 4-fluorophenyl ketone, 98%

MDL
MFCD00013728
EINECS
212-247-3

Chemische Eigenschaften

Formel
C10H9FO
Molmasse
164.18
Siedepunkt
119-120°/13mm
Flammpunkt
100°(212°F)
Dichte
1.144
Brechungsindex
1.5320
Löslichkeit
Not miscible with water.

Anwendungen

It is used in medicine. Indoles undergo smooth alkylation with cyclopropyl ketones in the presence of the CeCl3·7H2O/LiI reagent system in refluxing acetonitrile under neutral conditions to produce the corresponding C-3 substituted indole derivatives in good to high yields and with high selectivity.

Bemerkungen

Store at room temperature. Keep away from oxidizing agents.

Literaturverweise

R. Garth Pews.; N. D. Ojha. Electronic properties of three-membered rings. II. Transmission of conjugation by the cyclopropane ring.J. Am. Chem. Soc. 1969, 91 (21),5769-5773 .

Takanori Tanaka.; Yorinobu Yasuda.; Masahiko Hayashi. New Chiral Schiff Base as a Tridentate Ligand for Catalytic Enantioselective Addition of Diethylzinc to Aldehydes J. Org. Chem. 2006, 71 (7091-7093), .

Weitere Referenzen

Beilstein
2044844
Harmonized Tariff Code
2914.70
TSCA
No

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Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf