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3972-65-4 - 1-Bromo-4-tert-butylbenzene, 97% - 4-tert-Butylbromobenzene - A15924 - Alfa Aesar

A15924 1-Bromo-4-tert-butylbenzene, 97%

CAS-Nummer
3972-65-4
Synonyme
4-tert-Butylbromobenzene

Größe Preis ($) Menge Verfügbarkeit
25g 49,48
100g 139,95
500g 443,20
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1-Bromo-4-tert-butylbenzene, 97%

MDL
MFCD00000108
EINECS
223-599-2

Chemische Eigenschaften

Formel
C10H13Br
Molmasse
213.12
Schmelzpunkt
15-16°
Siedepunkt
231-232°
Flammpunkt
97°(206°F)
Dichte
1.229
Brechungsindex
1.5330
Löslichkeit
Insoluble in water.

Anwendungen

1-Bromo-4-tert-butylbenzene was used in the synthesis of 4-tert-butyl-phenylboronic acid1, 1-deoxy analogs of CP-47,497 (n = 0 to 7) and 1-deoxy analogs of CP-55,940 (n = 0 to 7). It undergoes lithium-bromide exchange reactions with n-butyllithium and tert-butyllithium at 0°C in various solvents.

Bemerkungen

Store in cool dry place. Keep away from oxidizing agents.

Literaturverweise

Michael Palucki.; Stephen L. Buchwald. Palladium-Catalyzed α-Arylation of Ketones.J. Am. Chem. Soc. 1997, 119 (45),11108-11109 .

Jens Åhman.; John P. Wolfe.; Malisa V. Troutman.; Michael Palucki.; Stephen L. Buchwald. Asymmetric Arylation of Ketone Enolates.J. Am. Chem. Soc. 1998, 120 (8), 1918-1919 .

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1859117
Harmonized Tariff Code
2903.99
TSCA
No

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