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Calcium chloride is used as an efficient drying agent for aprotic base-stable solvents like ethers and tertiary amines. It is a useful dehydrating agent in a synthesis of aldehyde enamines in high yield and purity.
Efficient drying agent for aprotic, base-stable solvents, particularly useful for ethers and tertiary amines.
Has been used as a dehydrating agent in a synthesis of aldehyde enamines in high yield and purity: Synth. Commun., 24, 1541 (1994).
Liu, Y.; Wang, X.; Liu, H.; Dong, Z.; Li, S.; Ge, H.; Yan, M. Investigation on the improved hydrolysis of aluminum-calcium hydride-salt mixture elaborated by ball milling. Energy 2015, 84, 714-721.
Leich, V.; Spaniol, T. P.; Okuda, J. Formation of a Cationic Calcium Hydride Cluster with a Naked Triphenylsilyl Anion by Hydrogenolysis of Bis(triphenylsilyl)calcium. Inorg. Chem. 2015, 54 (10), 4927-4933.
Gefahrenhinweise (EU): H260
In contact with water releases flammable gases which may ignite spontaneously.
Keep away from any possible contact with water, because of violent reaction and possible flash fire. Handle under inert gas. Protect from moisture. Wear protective gloves and eye/face protection. In case of fire: Use for extinction: CO2, sand, extinguishing powder. Store in a dry place. Store in a closed container. Dispose of contents/container in accordance with local/regional/national/international regulations.