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108-05-4 - Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone - Acetic acid vinyl ester - A16247 - Alfa Aesar

A16247 Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

CAS-Nummer
108-05-4
Synonyme
Acetic acid vinyl ester

Größe Preis ($) Menge Verfügbarkeit
100ml 18,64
500ml 22,05
2500ml 47,28
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Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

MDL
MFCD00008713
EINECS
203-545-4

Chemische Eigenschaften

Formel
C4H6O2
Molmasse
86.09
Schmelzpunkt
-100°
Siedepunkt
72-73°
Flammpunkt
-8°(18°F)
Dichte
0.932
Brechungsindex
1.3960
Löslichkeit
Slightly miscible with water.

Anwendungen

Vinyl acetate is used in the preparation of polyvinyl acetate emulsions and polyvinyl alcohol. It acts as a precursor to polyvinyl acetate. It serves as an ingredient in furniture-glue. It is also used to prepare copolymers with other monomers such as ethylene, acrylic acid. Further, it is used to make adhesives, paints and plastics.

Bemerkungen

Light sensitive. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid and 2-aminoethanol.

Literaturverweise

For example of mercuric acetate-catalyzed transesterification to long-chain vinyl esters, see: Org. Synth. Coll., 4, 977 (1963).

For thermal [2+2] cycloaddition with chlorotrifluoroethylene, see: Org. Synth. Coll., 5, 235 (1973); and with chlorosulfonyl isocyanate to give a ß-lactam: Org. Synth. Coll., 8, 3 (1993).

Dong, X.; Guan, X.; Jiang, Y.; Ma, J.; Zhang, M. Extension of the TraPPE-UA force field to the simulation of vapor-liquid phase equilibria of vinyl acetate system. J. Mol. Liq. 2015, 209, 520-525.

Belbekhouche, S.; Picton, L.; Le Cerf, D.; Hamaide, T. Pullulan-Based Polymer Surfactants for Vinyl Acetate Miniemulsion Polymerization: Kinetics and Colloidal Stability Investigations. Macromol. Chem. Phys. 2015, 216 (18), 1879-1887.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H351-H332-H335-H303-H313

Highly flammable liquid and vapour. Suspected of causing cancer. Harmful if inhaled. May cause respiratory irritation. May be harmful if swallowed. May be harmful in contact with skin.

Sicherheitshinweise: P210-P201-P261-P280-P281-P240-P303+P361+P353-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,9992
Beilstein
1209327
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2915.32
TSCA
Yes
RTECS
AK0875000

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