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5892-11-5 - Brucine dihydrate, 98% - A16251 - Alfa Aesar

A16251 Brucine dihydrate, 98%

CAS-Nummer
5892-11-5
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 36,46
50g 92,70
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Brucine dihydrate, 98%

MDL
MFCD00149384

Chemische Eigenschaften

Formel
C23H26N2O4•2H2O
Molmasse
430.50 (394.47anhy)
Schmelzpunkt
176-178°
Löslichkeit
Soluble in methanol. Partially soluble Miscible with water.

Anwendungen

Resolving agentBrucine dihydrate is used as a resolving agent for chiral acids.

Bemerkungen

Incompatible with strong oxidizing agents, bases and strong reducing agents.

Literaturverweise

Resolving agent for chiral acids.

Białon?ska, A.; Ciunik, Z.; Ilczyszyn, M. M.; Siczek, M. Discrete Cuboidal 15- and 16-Membered Water Clusters in Brucine 3.86-Hydrate, Water Release and Its Consequences. Cryst. Growth Des. 2014, 14 (12), 6537-6541.

Smith, G.; Wermuth, U. D.; Williams, M. L. Resolution of the Chiral (1R,2S) Enantiomer of cis-Cyclohexane-1,2-dicarboxylic Acid in the Brucinium Salt 2,3-Dimethoxy-10-oxostrychnidinium (1R,2S)-2-carboxycyclohexane-1-carboxylate Dihydrate. J. Chem. Crystallogr. 2012, 42 (6), 555-559.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H300-H330-H402-H412

Fatal if swallowed. Fatal if inhaled. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Sicherheitshinweise: P260-P284-P273-P301+P310-P304+P340-P320-P330-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. Avoid release to the environment. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
I
Harmonized Tariff Code
2939.99
TSCA
Yes

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