Methyl carbamate was used in the synthesis of protected aminocyclopropanes.
Qi-Feng Li,; Jun-Wei Wang,; Wen-Sheng Dong,; Mao-Qing Kang,; Xin-Kui Wang,; Shao-Yi Peng. A phosgene-free process for the synthesis of methyl N-phenyl carbamate by the reaction of aniline with methyl carbamate. Journal of Molecular Catalysis A: Chemical. 2004, 212 (1-2), 99-105.
The Na derivative has been used as an ammonia equivalent in the Pd(0)-catalyzed amination of allylic acetates: Chem. Lett., 2123 (1989).
Gefahrenhinweise (EU): H315-H319-H351-H335
Causes skin irritation. Causes serious eye irritation. Suspected of causing cancer. May cause respiratory irritation.
Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.