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10420-89-0 - (S)-(-)-1-(1-Naphthyl)ethylamine, 99% - A17176 - Alfa Aesar

A17176 (S)-(-)-1-(1-Naphthyl)ethylamine, 99%

CAS-Nummer
10420-89-0
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 38,88
5g 150,38
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(S)-(-)-1-(1-Naphthyl)ethylamine, 99%

MDL
MFCD00064179

Chemische Eigenschaften

Formel
C12H13N
Molmasse
171.24
Siedepunkt
152-153°/11mm
Flammpunkt
>110°(230°F)
Dichte
1.060
Brechungsindex
1.6230
Sensitivität
Air Sensitive
Löslichkeit
Soluble in chloroform, ethanol.

Anwendungen

(S)-(-)-1-(1-Naphthyl)ethylamine, (S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.

Bemerkungen

Air Sensitive. Stable under recommended storage conditions. Keep away from acids, acid chlorides, acid anhydrides, oxidizing agents, chloroformates.

Literaturverweise

JM Bonello.; FJ Williams. Aspects of enantioselective heterogeneous catalysis: Structure and reactivity of (S)-(-)-1-(1-naphthyl) ethylamine on Pt {111}. J. Am. Chem. Soc. 2003125 (9),  2723-2729.

NW Alcock.; JM Brown.; DI Hulmes. Synthesis and resolution of 1-(2-diphenylphosphino-1-naphthyl) isoquinoline; a P? N chelating ligand for asymmetric catalysis. Tetrahedron: Asymmetry. 19934 (4), 743-756.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H312-H314-H318

Toxic if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Beilstein
2208024
Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2921.49
TSCA
Yes

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