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838-57-3 - Ethyl 4-nitrobenzoylacetate, 97% - 4-Nitrobenzoylacetic acid ethyl ester - A17603 - Alfa Aesar

A17603 Ethyl 4-nitrobenzoylacetate, 97%

CAS-Nummer
838-57-3
Synonyme
4-Nitrobenzoylacetic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
10g 59,12
50g 260,59
250g 841,60
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Ethyl 4-nitrobenzoylacetate, 97%

MDL
MFCD00007357
EINECS
212-656-7

Chemische Eigenschaften

Formel
C11H11NO5
Molmasse
237.21
Schmelzpunkt
68-73°

Anwendungen

It is employed as a reactant involved in synthesis of β-1,3-dicarbonyl aldehydes via oxidation, knoevenagel condensation using a lysine catalyst, and cycloisomerization for the synthesis of trisubstituted furans. It is also a reactant for the fluorination by HF and iodosylbenzene, intramolecular Michael addition reactions and synthesis of diols. Also applied in the synthesis of diols via reduction of aromatic and aliphatic ketos esters6 and cross-coupling reactions for stereo selective synthesis of unsymmetrical 1,4-enediones.

Bemerkungen

Store away from oxidizing agents. Keep the container tightly closed in a cool, dry place.

Literaturverweise

Weiping Liu.; Jinhua Liu.; Daisuke Ogawa.; Yasushi Nishihara.; Xingwei Guo.; Zhiping Li. Iron-catalyzed oxidation of tertiary amines: synthesis of β-1,3-dicarbonyl aldehydes by three-component C-C couplings.Org Lett.,2011,13(23), 6272-6275.

Tsugio Kitamura.; Satoshi Kuriki.; Mohammad Hasan Morshed.; Yuji Hori. A practical and convenient fluorination of 1,3-dicarbonyl compounds using aqueous HF in the presence of iodosylbenzene.Org Lett.2011,13(9), 2392-2394.

Weitere Referenzen

Beilstein
1124763
Harmonized Tariff Code
2918.30
TSCA
Yes
RTECS
AJ1073500

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