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696-71-9 - Cyclooctanol, 97% - A17825 - Alfa Aesar

A17825 Cyclooctanol, 97%

CAS-Nummer
696-71-9
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25g 56,75
100g 180,25
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Cyclooctanol, 97%

MDL
MFCD00001744
EINECS
211-800-6

Chemische Eigenschaften

Formel
C8H16O
Molmasse
128.22
Schmelzpunkt
14-15°
Siedepunkt
97-98°/11mm
Flammpunkt
86°(186°F)
Dichte
0.970
Brechungsindex
1.4860
Löslichkeit
Miscible with acetone.

Anwendungen

Cyclooctanol is a key starting material used for the preparation of cylooctanone by using a chromic acid reagent.

Bemerkungen

Contains 75+% cyclopentane; remainder consists of C{5} and C{6} hydrocarbon.Incompatible with strong oxidizing agents, acid chloride, and acid anhydrides.

Literaturverweise

Oxidation of secondary alcohols to ketones with chromic acid in acetone (Jones' reagent) is exemplified for the preparation of cyclooctanone: Org. Synth. Coll., 5, 310 (1973).

Ren, Y.; Cheng, X.; Yang, K.; Zhu, X.; Li, H.; Wang, Y. Raman study of plastic crystal phase of cyclooctanol under high pressure with different compression rate. J. Mol. Struct. 2015, 1012, 6-10.

Huang, Y. B.; Shen, M.; Wang, X.; Shi, P. C.; Li, H.; Cao, R. Hierarchically micro- and mesoporous metal-organic framework-supported alloy nanocrystals as bifunctional catalysts: Toward cooperative catalysis. J. Catal. 2015, 330, 452-457.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H315-H319-H227

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Combustible liquid.

Sicherheitshinweise: P210-P280-P305+P351+P338-P362-P301+P312-P321-P332+P313-P337+P313-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1848166
Harmonized Tariff Code
2906.19
TSCA
No

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