Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

58109-40-3 - Diphenyliodonium hexafluorophosphate, 98% - A17934 - Alfa Aesar

A17934 Diphenyliodonium hexafluorophosphate, 98%

CAS-Nummer
58109-40-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 76,84
50g 273,98
250g 792,80
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Diphenyliodonium hexafluorophosphate, 98%

MDL
MFCD00061398
EINECS
261-134-5

Chemische Eigenschaften

Formel
C12H10F6IP
Molmasse
426.08
Schmelzpunkt
139-144°
Sensitivität
Light Sensitive
Löslichkeit
Soluble in tetrahydrofuran, ethyl acetate, methanol, acetonitrile, dimethylformamide, dimethyl carbonate. Sparingly soluble in chloroform and dichloromethane. Insoluble in pentanes, hexanes, toluene and diethyl ether.

Anwendungen

Diphenyliodonium hexafluorophosphate is used as cationic photoinitiator and photoacid generator. It acts as a catalyst for the photochemical polymerization of various monomers. Further, it used as arylating reagent as well as an oxidant in organic synthesis.

Bemerkungen

Light sensitive and hygroscopic. Incompatible with strong acids.

Literaturverweise

Cahard, E.; Male, H. P. J.; Tissot, M.; Gaunt, M. J. Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts. J. Am. Chem. Soc. 2015, 137 (25), 7986-7989.

He, C.; Stoykovich, M. P. Photopatterning of Cross-Linkable Epoxide-Functionalized Block Copolymers and Dual-Tone Nanostructure Development for Fabrication Across the Nano-and Microscales. Small 2015, 11 (20), 2407-2416.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Harmonized Tariff Code
2931.90
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf