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Methyl 4-ethoxybenzoate is used in the preparation of 4- ethoxybenzoic acid by reacting with aluminum tribromide. It is involved in the preparation of apricoxib, which is a selective cyclooxygenase inhibitor.
Lee, J. J.; Pollock III, G. R.; Mitchell, D.; Kasuga, L.; Kraus, G. A. Upgrading malic acid to bio-based benzoates via a Diels-Alder-initiated sequence with the methyl coumalate platform. RSC Adv. 2014, 4 (86), 45657-45664.
Yamanaka, M.; Kobayashi, K. Capsular Assemblies of Calixresorcinarene-based Cavitands. Asian J. Org. Chem. 2013, 2 (4), 276-289.