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615-41-8 - 1-Chloro-2-iodobenzene, 99% - 2-Chloroiodobenzene - A18255 - Alfa Aesar

A18255 1-Chloro-2-iodobenzene, 99%

CAS-Nummer
615-41-8
Synonyme
2-Chloroiodobenzene

Größe Preis ($) Menge Verfügbarkeit
10g 26,10
25g 59,10
100g 189,00
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1-Chloro-2-iodobenzene, 99%

MDL
MFCD00001033
EINECS
210-423-4

Chemische Eigenschaften

Formel
C6H4ClI
Molmasse
238.46
Schmelzpunkt
Siedepunkt
108-110°/15mm
Flammpunkt
111°(231°F)
Dichte
1.954
Brechungsindex
1.6345
Sensitivität
Light Sensitive
Löslichkeit
Miscible with most common organic solvents. Immiscible with water.

Anwendungen

1-Chloro-2-iodobenzene is used as a precursor and involved in the preparation of 2,2'-dichloro-biphenyl. It is also used to prepare N,N-diaryl-o-phenylenediamines and 4(5)-(2-chlorophenyl)-1H-imidazole. It reacts with lanthanum metal in the presence of trimethylchlorosilane to prepare 1-chloro-2-trimethylsilylbenzene.

Bemerkungen

Light sensitive. Incompatible with strong oxidizing agents, strong acids and bases. Store in a cool place. Keep the container tightly closed.

Literaturverweise

Xu, Z.; Yang, T.; Lin, X.; Elliott, J. D.; Ren, F. A mild and efficient carboxylate-directed C-H arylation of aryl carboxylic acids with iodobenzenes in water. Tetrahedron Lett. 2015, 56 (2), 475-477.

Rotta-Loria, N. L.; Borzenko, A.; Alsabeh, P. G.; Lavery, C. B.; Stradiotto, M. Utilizing Mor-DalPhos/Palladium-Catalyzed Monoarylation in the Multicomponent One-Pot Synthesis of Indoles. Adv. Synth. Catal. 2015, 357 (1), 100-106.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1905116
Harmonized Tariff Code
2903.99
TSCA
Yes

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