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6609-64-9 - Ethylene chlorophosphate, 95% - 2-Chloro-1,3,2-dioxaphospholane 2-oxide - 2-Chloro-2-oxo-1,3,2-dioxaphospholane - A18320 - Alfa Aesar

A18320 Ethylene chlorophosphate, 95%

CAS-Nummer
6609-64-9
Synonyme
2-Chloro-1,3,2-dioxaphospholane 2-oxide
2-Chloro-2-oxo-1,3,2-dioxaphospholane

Größe Preis ($) Menge Verfügbarkeit
5g 60,56
25g 232,78
100g 745,72
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Ethylene chlorophosphate, 95%

MDL
MFCD00043138
EINECS
229-560-6

Chemische Eigenschaften

Formel
C2H4ClO3P
Molmasse
142.48
Schmelzpunkt
12-14°
Siedepunkt
98-99°/2mm
Flammpunkt
>110°(230°F)
Dichte
1.56
Brechungsindex
1.4500
Sensitivität
Moisture Sensitive
Löslichkeit
Miscible with water and chloroform.

Anwendungen

Ethylene chlorophosphate is used in the syntheses of 2-methacryloyoxyethylphophocholine, phosphatidylcholines, 2',3'-O-16-hentriacontanyliden-adenosine-5'-phosphocholine and hexadecylphosphocholine. It is also involved the synthesis of alpha-naphthylphosphorylcholine, which is used to detect phospholipase C activity. It is an important reactant for the synthesis of a zwitterionic silane, UV-polymerizable lipids utilizing Chabrier reaction and block copolymers of poly(aliphatic ester) clickable polyphosphoester.

Bemerkungen

Store in cool place. Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water and reacts violently.

Literaturverweise

Hu, G.; Parelkar, S. S.; & Emrick, T. A facile approach to hydrophilic, reverse zwitterionic, choline phosphate polymers. Polym. Chem. 2015, 6 (4), 525-530.

Rosseto, R.; Hajdu, J. Synthesis of phospholipids on a glyceric acid scaffold: design and preparation of phospholipase A 2 specific substrates. Tetrahedron 2014, 70 (19), 3155-3165.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
606582
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2934.99
TSCA
No

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