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Diallylamine is used as an intermediate for ion exchange resins, pharmaceuticals, water soluble polymers, rubber chemicals, polymerization initiators and cross-linking agents.
Florence Garro-Helion; Ahmed Merzouk; Francois Guibe. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines. J. Org. Chem., 1993, 58 (22), 6109-6113.
Susumu Harada; and Masamichi Katayama. The cyclo-copolymerization of diallyl compound and sulfur dioxide. I. Diallylamine hydrochloride and sulfur dioxide. Journal of Bacteriology, 1966, 90(1), 177-186.
Pd catalyzed coupling with aryl or heteroaryl halides followed by cleavage with methanesulfonic acid or BF3 etherate in the presence of Pd on carbon, provides a mild route to aryl or heteroaryl amines in which the diallylamine behaves as an ammonia equivalent: Tetrahedron Lett., 39, 1313 (1998).
Gefahrenhinweise (EU): H225-H302-H311-H330-H314-H318
Highly flammable liquid and vapour. Harmful if swallowed. Toxic in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.