Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

56613-80-0 - (R)-(-)-2-Phenylglycinol, 98% - (R)-(-)-2-Amino-2-phenylethanol - H-D-Phg-ol - A19030 - Alfa Aesar

A19030 (R)-(-)-2-Phenylglycinol, 98%

CAS-Nummer
56613-80-0
Synonyme
(R)-(-)-2-Amino-2-phenylethanol
H-D-Phg-ol

Größe Preis ($) Menge Verfügbarkeit
1g 23,04
5g 68,16
25g 235,20
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

(R)-(-)-2-Phenylglycinol, 98%

MDL
MFCD00008062
EINECS
260-287-5

Chemische Eigenschaften

Formel
C8H11NO
Molmasse
137.18
Schmelzpunkt
76-78°
Sensitivität
Air Sensitive
Löslichkeit
Slightly soluble in water.

Anwendungen

Amino alcohol used to prepare a chiral imine or oxazolidine from ethyl trifluoropyruvate. These intermediates were then employed in a synthesis of both enantiomers of α-trifluoromethylproline. Chiral β-amino alcohol used as a synthetic building block.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Grégory Chaume et. al. Straightforward synthesis of (S)- and (R)-alpha-trifluoromethyl proline from chiral oxazolidines derived from ethyl trifluoropyruvate.. Organic Letters. 2006, 8 (26), 6123-6126.

Amberley S. Anslow,; Laurence M. Harwood,; Helen Phillips,; David Watkib .Development of a chiral stabilised azomethine ylid. A chiral relay system.. Tetrahedron: Asymmetry. year of publication , 2 (3), 169-172.

Condensation with glutaraldehyde gives a useful intermediate in asymmetric synthesis of alkaloids: Org. Synth. Coll., 9, 176 (1998):

Starting material for the enantioselective synthesis of 2,6-disubstituted piperazines: Synthesis, 833 (1996), and for chiral ɑ-amino phosphonates: Org. Synth., 75, 19 (1997).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2935848
Harmonized Tariff Code
2922.19
TSCA
No

Empfohlen

  • A10221

    Imidazole, 99%
  • A15952

    L-Methionine methyl ester hydrochloride, 99%
  • A19050

    N-Benzyloxycarbonyl-L-serine, 99%
  • L13265

    (S)-(+)-2-Phenylglycinol, 98+%
  • 35700

    Indium(I) iodide, ultra dry, 99.998% (metals basis)

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf