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41459-42-1 - 3-Bromo-2-(bromomethyl)propionic acid, 98% - Bis(bromomethyl)acetic acid - A19630 - Alfa Aesar

A19630 3-Bromo-2-(bromomethyl)propionic acid, 98%

CAS-Nummer
41459-42-1
Synonyme
Bis(bromomethyl)acetic acid

Größe Preis ($) Menge Verfügbarkeit
5g 61,29
25g 216,30
100g 638,60
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3-Bromo-2-(bromomethyl)propionic acid, 98%

MDL
MFCD00010643

Chemische Eigenschaften

Formel
(BrCH2)2CHCO2H
Molmasse
245.91
Schmelzpunkt
98-101°
Löslichkeit
Soluble in acetic acid.

Anwendungen

3-Bromo-2-(bromomethyl)propionic acid acts as an organic building block for the preparation of beta-substituted acrylates. It is used in the preparation of t-butyl 2-(phenylthiomethyl) propenoate, t-butyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl-sulfinylmethyl)propenoate. Further, it plays an important role in the synthesis of beta-lactams by cyclization of the corresponding amide.

Bemerkungen

Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Zhang, X.; Teixeira, V.; Porcal, W.; Cabral, P.; Gambini, J. P.; Fernandez, M.; Gallazzi, F.; Quinn, T. P. [99mTc(CO)3]+ and [99mTcO2]+ Radiolabeled Cyclic Melanotropin Peptides for Melanoma SPECT Imaging. Curr. Radiopharm. 2014, 7 (1), 63-74.

Hicks, M. R.; Rullay, A. K.; Pedrido, R.; Crout, D. H.; Pinheiro, T. J. T. Efficient Synthesis of Methanesulphonate-Derived Lipid Chains for Attachment of Proteins to Lipid Membranes. Synth. Commun. 2008, 38 (21), 3726-3750.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
8
Verpackungsgruppe
III
Harmonized Tariff Code
2915.90
TSCA
No

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