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Pentafluoropyridine was used in the preparation of η2-C,C coordinated pentafluoropyridine complex. It was also used in the preparation of polyfluorinated coupling products via Pd(0)-catalyzed cross-coupling reaction with diarylzinc compounds. It was also used as derivatizing reagent in the sensitive GC-MS method for determination of the four endocrine disrupting chemicals.
Procacci B.; Blagg RJ.; Perutz RN, et al. Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction.Organometallics.2014,33(1), 45-52.
Masato Ohashi, et al. Palladium-catalyzed coupling reaction of perfluoroarenes with diarylzinc compounds.Chemistry.2014,20(7), 2040-2048.
Protection of alcohols has been effected under phase-transfer conditions to give preferentially the 4-alkoxy-derivatives which can be cleaved with sodium methoxide in DMF: J. Chem. Soc., Chem. Commun., 125 (1984).
Gefahrenhinweise (EU): H226-H302-H312-H332-H314-H318
Flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.