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A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.
Hongjun Ren.; Guillaume Dunet.; Peter Mayer.; Paul Knochel. Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents.J. Am. Chem. Soc. 2007, 129 (17),5376-5377 .
Robert J. Hinkle.; Alessandra C. Leri.; Geoffrey A. David. ;Whitney M. Erwin. Addition of Benzylzinc Halides to Alkenyl(phenyl)iodonium Triflates:? Stereoselective Synthesis of Trisubstituted Alkenes.Org. Lett.. 2000, 2 (11),1521-1523 .
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
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