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10202-75-2 - 4-Allyl-1,6-heptadien-4-ol, 99% - Triallyl carbinol - B20703 - Alfa Aesar

B20703 4-Allyl-1,6-heptadien-4-ol, 99%

CAS-Nummer
10202-75-2
Synonyme
Triallyl carbinol

Größe Preis ($) Menge Verfügbarkeit
2.5g 31,93
10g 69,76
50g 269,60
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4-Allyl-1,6-heptadien-4-ol, 99%

MDL
MFCD00039829

Chemische Eigenschaften

Formel
(CH2=CHCH2)3COH
Molmasse
152.24
Löslichkeit
Soluble in water.

Anwendungen

A highly diastereoselective synthesis of homoallylic alcohols bearing up to two adjacent quaternary centers was achieved using these polysubstituted allylic reagents.

Bemerkungen

Store at room temperature. Incompatible with strong oxidizing agents.

Literaturverweise

Hongjun Ren.; Guillaume Dunet.; Peter Mayer.; Paul Knochel. Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents.J. Am. Chem. Soc. 2007, 129 (17),5376-5377 .

Robert J. Hinkle.; Alessandra C. Leri.; Geoffrey A. David. ;Whitney M. Erwin. Addition of Benzylzinc Halides to Alkenyl(phenyl)iodonium Triflates:? Stereoselective Synthesis of Trisubstituted Alkenes.Org. Lett.. 2000, 2 (11),1521-1523 .

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2905.29
TSCA
No

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