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20986-40-7 - Ethyl 5-bromonicotinate, 98% - 5-Bromonicotinic acid ethyl ester - Ethyl 5-bromopyridine-3-carboxylate - B20788 - Alfa Aesar

B20788 Ethyl 5-bromonicotinate, 98%

CAS-Nummer
20986-40-7
Synonyme
5-Bromonicotinic acid ethyl ester
Ethyl 5-bromopyridine-3-carboxylate

Größe Preis ($) Menge Verfügbarkeit
1g 45,70
5g 176,00
25g 688,00
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Ethyl 5-bromonicotinate, 98%

MDL
MFCD00040366

Chemische Eigenschaften

Formel
C8H8BrNO2
Molmasse
230.07
Schmelzpunkt
39-42°
Siedepunkt
86-92°/0.5mm

Anwendungen

Ethyl 5-bromonicotinate is used as a key starting material for the preparation of 5-bromonicotinic acid hydrazide via reaction with a hydrazine hydrate.

Bemerkungen

Incompatible with oxidizing agents.

Literaturverweise

Houllier, N.; Lasne, M. C.; Bureau, R.; Lestage, P.; Rouden, J. Synthesis of a cytisine/epibatidine hybrid: a radical approach. Tetrahedron 2010, 66 (47), 9231-9241.

Melzig, L.; Dennenwaldt, T.; Gavryushin, A.; Knochel, P. Direct aminoalkylation of arenes, heteroarenes, and alkenes via Ni-catalyzed Negishi cross-coupling reactions. J. Org. Chem 2011, 76 (21), 8891-8906.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
131473
Harmonized Tariff Code
2933.39
TSCA
No

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