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29681-44-5 - Methyl 5-bromonicotinate, 97% - 5-Bromopyridine-3-carboxylic acid methyl ester - Methyl 5-bromopyridine-3-carboxylate - B20908 - Alfa Aesar

B20908 Methyl 5-bromonicotinate, 97%

CAS-Nummer
29681-44-5
Synonyme
5-Bromopyridine-3-carboxylic acid methyl ester
Methyl 5-bromopyridine-3-carboxylate

Größe Preis ($) Menge Verfügbarkeit
1g 26,47
5g 106,09
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Methyl 5-bromonicotinate, 97%

MDL
MFCD00173668

Chemische Eigenschaften

Formel
C7H6BrNO2
Molmasse
216.04
Schmelzpunkt
96-98°
Löslichkeit
Slightly soluble in water.

Anwendungen

A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.

Bemerkungen

Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Wayne J. Thompson, et al. A general synthesis of 5-arylnicotinates.J. Org. Chem.,1984,49(26), 5237-5243.

Masahiko Iyoda, et al. Homocoupling of Aryl Halides Using Nickel(II) Complex and Zinc in the Presence of Et4NI. An Efficient Method for the Synthesis of Biaryls and Bipyridines.Bull. Chem. Soc. Jpn.,1990,63(1), 80-87.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2933.39
TSCA
No

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