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A substrate used in a microwave-assisted, palladium-catalyzed arylation of acetone as its TMS enol ether.
Wayne J. Thompson, et al. A general synthesis of 5-arylnicotinates.J. Org. Chem.,1984,49(26), 5237-5243.
Masahiko Iyoda, et al. Homocoupling of Aryl Halides Using Nickel(II) Complex and Zinc in the Presence of Et4NI. An Efficient Method for the Synthesis of Biaryls and Bipyridines.Bull. Chem. Soc. Jpn.,1990,63(1), 80-87.
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.