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355-43-1 - Perfluoro-1-iodohexane, 98+%, stab. with copper - 1-Iodoperfluorohexane - Perfluoro-n-hexyl iodide - B20958 - Alfa Aesar

B20958 Perfluoro-1-iodohexane, 98+%, stab. with copper

CAS-Nummer
355-43-1
Synonyme
1-Iodoperfluorohexane
Perfluoro-n-hexyl iodide

Größe Preis ($) Menge Verfügbarkeit
10g 35,90
50g 138,00
250g 546,00
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Perfluoro-1-iodohexane, 98+%, stab. with copper

MDL
MFCD00001063
EINECS
206-586-6

Chemische Eigenschaften

Formel
CF3(CF2)5I
Molmasse
445.95
Schmelzpunkt
-45°
Siedepunkt
117°
Dichte
2.063
Brechungsindex
1.3290
Sensitivität
Light Sensitive
Löslichkeit
Not miscible or difficult to mix in water.

Anwendungen

It is used as an initiator in the presence of fac-[Ir(ppy) 3 for the photoredox catalyst activated CRP of methacrylates in visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide.

Bemerkungen

Light sensitive. Store away from light and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Qian Liu, et al. Visible light-induced controlled radical polymerization of methacrylates with perfluoroalkyl iodide as the initiator in conjugation with a photoredox catalyst fac-[Ir(ppy)]3.J. Polym. Sci.,2014,52(22), 3283-3291.

Emily R. Berkeley,et al. Syntheses, Structural Characterizations, and Reactivity Studies of Half-Sandwich Cobalt, Rhodium, and Iridium Metallatricarbadecaboranyl Complexes.Organometallics.,2015,34(7), 1396-1407.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1802118
Harmonized Tariff Code
2903.78
TSCA
Yes

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