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1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.
Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).
Li, C. G.; Xue, F.; Cui, M. J.; Shang, J. Y.; Lou, T. J. 1,1'-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons. Transition Met. Chem. 2015, 40 (1), 47-52.
Kaur-Ghumaan, S.; Sreenithya, A.; Sunoj, R. B. Synthesis, characterization and DFT studies of 1, 1'-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes. J. Chem. Sci. 2015, 127 (3), 557-563.
Gefahrenhinweise (EU): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
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