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12150-46-8 - 1,1'-Bis(diphenylphosphino)ferrocene, 97% - Dppf - 1,1'-Ferrocenebis(diphenylphosphine) - B21166 - Alfa Aesar

B21166 1,1'-Bis(diphenylphosphino)ferrocene, 97%

CAS-Nummer
12150-46-8
Synonyme
Dppf
1,1'-Ferrocenebis(diphenylphosphine)

Größe Preis ($) Menge Verfügbarkeit
1g 34,10
5g 96,60
25g 433,00
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1,1'-Bis(diphenylphosphino)ferrocene, 97%

MDL
MFCD00001422

Chemische Eigenschaften

Formel
C34H28FeP2
Molmasse
554.40
Schmelzpunkt
ca 182° dec.
Sensitivität
Air Sensitive
Löslichkeit
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Anwendungen

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Bemerkungen

Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Literaturverweise

Hindered bidentate ligand used in, for example, the Ni-catalyzed Suzuki-type crossed coupling of arylboronic acids with aryl mesylates to give biaryls: J. Org. Chem., 60, 1060, 1066 (1995), and of thiophenolates with aryl mesylates to give unsymmetrical diaryl sulfides: J. Org. Chem., 60, 6895 (1995).

Li, C. G.; Xue, F.; Cui, M. J.; Shang, J. Y.; Lou, T. J. 1,1'-bis(diphenylphosphino)ferrocene as an intramolecular or intermolecular bridging ligand related to the phenyl-functionalized diiron propanedithiolate complex: synthesis and catalysis of the reduction of protons. Transition Met. Chem. 2015, 40 (1), 47-52.

Kaur-Ghumaan, S.; Sreenithya, A.; Sunoj, R. B. Synthesis, characterization and DFT studies of 1, 1'-Bis(diphenylphosphino)ferrocene substituted diiron complexes: Bioinspired [FeFe] hydrogenase model complexes. J. Chem. Sci. 2015, 127 (3), 557-563.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Harmonized Tariff Code
2931.39
TSCA
No

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