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41825-73-4 - 2-Bromo-4,6-dimethylaniline, 98% - B21272 - Alfa Aesar

B21272 2-Bromo-4,6-dimethylaniline, 98%

CAS-Nummer
41825-73-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 40,72
25g 91,08
50g 153,17
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2-Bromo-4,6-dimethylaniline, 98%

MDL
MFCD00047826
EINECS
246-337-9

Chemische Eigenschaften

Formel
C8H10BrN
Molmasse
200.08
Schmelzpunkt
42-46°
Siedepunkt
75-79°/5mm
Flammpunkt
>110°(230°F)
Löslichkeit
Insoluble in water.

Anwendungen

2-Bromo-4,6-dimethylaniline can react with 3-chloro-3-methyl-but-1-yne to produce 2-bromo-N-(1',1'-dimethylprop-2'-ynyl)-4,6-dimethylaniline. This reaction will need reagent Et3N, catalyst CuCl, and the menstruum dioxane.

Bemerkungen

Keep container tightly closed. Store away from oxidizing agents.

Literaturverweise

Rattan K. Gujadhur.; Craig G. Bates.; D. Venkataraman. Formation of Aryl-Nitrogen, Aryl-Oxygen, and Aryl-Carbon Bonds Using Well-Defined Copper(I)-Based Catalysts. Org. Lett. 2001, 3, (26), 4315-4317.

Fuk Yee Kwong.; Artis Klapars.; Stephen L. Buchwald. Copper-Catalyzed Coupling of Alkylamines and Aryl Iodides:? An Efficient System Even in an Air Atmospheres. Org. Lett. 2002, 4, (4), 581-584.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H331-H302-H312-H315-H319-H373

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause damage to organs through prolonged or repeated exposure.

Sicherheitshinweise: P260-P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
3046484
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2921.42
TSCA
No

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