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118-29-6 - N-(Hydroxymethyl)phthalimide, 97% - B21292 - Alfa Aesar

B21292 N-(Hydroxymethyl)phthalimide, 97%

CAS-Nummer
118-29-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
25g 20,40
100g 54,50
500g 223,00
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N-(Hydroxymethyl)phthalimide, 97%

MDL
MFCD00005899
EINECS
204-241-4

Chemische Eigenschaften

Formel
C9H7NO3
Molmasse
177.16
Schmelzpunkt
140-147°

Literaturverweise

Used for the introduction of the phthalimidomethyl group by electrophilic substitution of aromatic compounds. For reviews on this amidomethylation reaction, see: Org. React., 14, 52 (1965); Synthesis, 49, (1970); 85, 181 (1984).

/n

In the presence of diethylamine, protection of carboxylic acids as phthalimidomethyl esters has been reported. The group can be cleaved with hydrazine in MeOH, by a variety of basic or acidic conditions: Rec. Trav. Chim., 82, 941 (1963), or with Zn in AcOH: Chem. Ind. (London), 1204 (1970).

/n

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
140946
Harmonized Tariff Code
2925.19
TSCA
Yes
RTECS
TI5270000

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