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401-55-8 - Ethyl bromofluoroacetate, 97% - Bromofluoroacetic acid ethyl ester - B21579 - Alfa Aesar

B21579 Ethyl bromofluoroacetate, 97%

CAS-Nummer
401-55-8
Synonyme
Bromofluoroacetic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 16,10
5g 37,50
25g 138,00
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Ethyl bromofluoroacetate, 97%

MDL
MFCD00042095
EINECS
206-928-4

Chemische Eigenschaften

Formel
FBrCHCO2CH2CH3
Molmasse
184.99
Siedepunkt
154°
Flammpunkt
70°(158°F)
Dichte
1.540
Brechungsindex
1.4255
Löslichkeit
It is soluble in water.

Anwendungen

Ethyl bromofluoroacetate is used as an intermediate useful in the synthesis of polyfluoroalkyl-substituted fluoro enol ethers and N-protected α-fluoroglycines.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literaturverweise

R Ocampo.; WR Dolbier.; KA Abboud. Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of α-fluoro-β-hydroxy acids. J. Org. Chem. 200267 (1), 72-78.

Undergoes Reformatsky reactions with Zn and carbonyl compounds under various conditions. Superior results have been obtained in the presence of a catalytic amount of CeCl3: J. Org. Chem., 67, 72 (2002):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227-H301-H311-H331-H315-H318-H335

Combustible liquid. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye damage. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2915.90
TSCA
No

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