Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

401-55-8 - Ethyl bromofluoroacetate, 97% - Bromofluoroacetic acid ethyl ester - B21579 - Alfa Aesar

B21579 Ethyl bromofluoroacetate, 97%

CAS-Nummer
401-55-8
Synonyme
Bromofluoroacetic acid ethyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 10,05
5g 33,60
25g 112,35
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Ethyl bromofluoroacetate, 97%

MDL
MFCD00042095
EINECS
206-928-4

Chemische Eigenschaften

Formel
FBrCHCO2CH2CH3
Molmasse
184.99
Siedepunkt
154°
Flammpunkt
70°(158°F)
Dichte
1.540
Brechungsindex
1.4255
Löslichkeit
It is soluble in water.

Anwendungen

Ethyl bromofluoroacetate is used as an intermediate useful in the synthesis of polyfluoroalkyl-substituted fluoro enol ethers and N-protected α-fluoroglycines.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away strong oxidizing agents.

Literaturverweise

R Ocampo.; WR Dolbier.; KA Abboud. Catalyzed Reformatsky reactions with ethyl bromofluoroacetate for the synthesis of α-fluoro-β-hydroxy acids. J. Org. Chem. 200267 (1), 72-78.

Undergoes Reformatsky reactions with Zn and carbonyl compounds under various conditions. Superior results have been obtained in the presence of a catalytic amount of CeCl3: J. Org. Chem., 67, 72 (2002):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H331-H315-H335-H318-H227

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. May cause respiratory irritation. Causes serious eye damage. Combustible liquid.

Sicherheitshinweise: P210-P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2915.90
TSCA
No

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf