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421-83-0 - Trifluoromethanesulfonyl chloride, 98% - Trifluoromethylsulfonyl chloride - Triflyl chloride - B21774 - Alfa Aesar

B21774 Trifluoromethanesulfonyl chloride, 98%

CAS-Nummer
421-83-0
Synonyme
Trifluoromethylsulfonyl chloride
Triflyl chloride

Größe Preis ($) Menge Verfügbarkeit
5g 52,70
25g 176,00
100g 711,00
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Trifluoromethanesulfonyl chloride, 98%

MDL
MFCD00007451
EINECS
207-009-0

Chemische Eigenschaften

Formel
CF3SO2Cl
Molmasse
168.52
Siedepunkt
32°
Dichte
1.593
Brechungsindex
1.3340
Sensitivität
Moisture Sensitive
Löslichkeit
Hydrolyzes with water.

Anwendungen

Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.

Bemerkungen

Moisture sensitive. Store away from water/moisture, heat and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.

Literaturverweise

Nobumasa Kamigata; Takeshi Ohtsuka; Takamasa Fukushima; Masato Yoshida; and Toshio Shimizu. Direct perfluoroalkylation of aromatic and heteroaromatic compounds with perfluoroalkanesulfonyl chlorides catalyzed by a ruthenium(II) phosphine complex.J. Chem. Soc., Perkin Trans. 1.19941339-1346.

Nobumasa Kamigata;Takamasa Fukushima; Yoshie Terakawa; Masato Yoshida; and Hideo Sawada. Novel perfluoroalkylation of alkenes with perfluoroalkanesulphonyl chlorides catalyzed by a ruthenium(II) complex.J. Chem. Soc., Perkin Trans. 1.1991(3), 627-633.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1812016
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2904.90
TSCA
No

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