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98946-18-0 - tert-Butyl 2,2,2-trichloroacetimidate, 97% - 2,2,2-Trichloroacetimidic acid tert-butyl ester - B22039 - Alfa Aesar

B22039 tert-Butyl 2,2,2-trichloroacetimidate, 97%

CAS-Nummer
98946-18-0
Synonyme
2,2,2-Trichloroacetimidic acid tert-butyl ester

Größe Preis ($) Menge Verfügbarkeit
1g 20,80
5g 55,10
25g 178,00
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tert-Butyl 2,2,2-trichloroacetimidate, 97%

MDL
MFCD00077410
EINECS
000-000-0

Chemische Eigenschaften

Formel
C6H10Cl3NO
Molmasse
218.51
Schmelzpunkt
20-22°
Siedepunkt
64-66°/15mm
Flammpunkt
55°(131°F)
Dichte
1.222
Brechungsindex
1.4570
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in organic solvents, cyclo hexane.

Anwendungen

tert-Butyl 2,2,2-trichloroacetimidate is used to produce di-tert-butyl peroxide at temperature of -5°C. It may be used in the synthesis of N-α-Fmoc-phospho(1-nitrophenylethyl-2-cyanoethyl)-L-serine, caged building block. It may be used in the conversion of alcohols and carboxylic acids to their respective ethers and esters.

Bemerkungen

Moisture sensitive. Store away from strong oxidizing agents, heat, water/ moisture.

Literaturverweise

Deborah M Rothman; M Eugenio Vazquez; Elizabeth M Vogel; Barbara Imperiali. Caged phospho-amino acid building blocks for solid-phase peptide synthesis. Journal of Organic Chemistry. 2003, 68 (17), 5150-5154.

Gary T. Wang; Sheldon Wang; Robert Gentles; Thomas Sowina; Clarence J. Maring; Dale J. Kempf; Warren M. Kati; Vincent Stoll;, Kent D. Stewart; Design, synthesis, and structural analysis of inhibitors of influenza neuraminidase containing a 2,3-disubstituted tetrahydrofuran-5-carboxylic acid core. Bioorganic & Medicinal Chemistry Letters. 2005, 15 (1-3), 125-128.

Reagent for preparation of t-butyl ethers and esters under mild conditions: J. Chem. Soc., Perkin 1, 2247 (1985); Tetrahedron Lett., 29, 2483 (1988). See also Appendix 6.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H315-H319-H335

Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1770049
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2925.29
TSCA
No

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