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B22214 1-Iodooctane, 98+%, stab. with copper

CAS-Nummer
629-27-6
Synonyme
n-Octyl iodide

Stock No. Größe Preis ($) Menge Verfügbarkeit
B22214-14 25g 27,20
B22214-22 100g 65,00
B22214-36 500g 248,00
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1-Iodooctane, 98+%, stab. with copper

MDL
MFCD00001105
EINECS
211-084-5

Chemische Eigenschaften

Formel
C8H17I
Molmasse
240.13
Schmelzpunkt
-46°
Siedepunkt
225-226°
Flammpunkt
95°(203°F)
Dichte
1.325
Brechungsindex
1.4878
Storage & Sensitivity
Light Sensitive. Ambient temperatures.
Löslichkeit
Insoluble in water.

Anwendungen

Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II)was performed using the catalytic reduction of 1-iodooctane. Primary alkyl iodide 1-iodooctane reacts with lithium aluminum deuteride (LAD) in a 1:0.2 ratio to form 1-deuteriooctane.

Bemerkungen

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light, bases.

Literaturverweise

Raess PW, et al. J. . Catalytic reduction of 1-iodooctane by nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide: Effects of added proton donors and a mechanism involving both metal-and ligand-centered one-electron reduction of nickel (II) salen. Electroanal. Chem. 2007, 603 (1), 124-34.

Danielle M Goken,; Dennis G Peters,; Jonathan A Karty,; James P Reilly. Alkylation of [2,2?-([2,2?-bipyridine]-6,6?-diyl)bis[phenolato]-N,N?,O,O?]nickel(II) during catalytic reduction of 1-iodooctane. Journal of Electroanalytical Chemistry. 2004, 564 123-132.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319

Causes skin irritation. Causes serious eye irritation.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1697479
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
RG9700100

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